Cocoa Powder Deconstructed


If you bake with cocoa you have probably noticed recipes that call for either Dutch-processed or natural (non-Dutch-processed) cocoa powder. Both types of cocoa powder are unsweetened and therefore bitter when tasted alone.

Dutch-Process Cocoa or Alkalized Unsweetened Cocoa Powder has been treated with an alkali to neutralize its natural acidity. Because it is neutral and does not react with baking soda, it must be used in recipes calling for baking powder, unless there are other acidic ingredients in sufficient quantities used. It has a reddish-brown color, mild flavor, and is easy to dissolve in liquids.
Unsweetened Cocoa has a complex chocolate flavor while the Dutch-process is darker and more mellow. Its intense flavor makes it well suited for use in brownies, cookies and some chocolate cakes. When natural cocoa (an acid) is used in recipes calling for baking soda (an alkali), it creates a leavening action that causes the batter to rise when placed in the oven.

It is important to use the type of cocoa specified in a recipe because it may affect the recipe's balance of acid. If you must substitute, use the following formula:

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